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Welcome to MOF4CAT

Metal-Organic-Frameworks (MOFs) offer appealing advantages over classical solids from combination of high surface areas with crystallinity and chemical/structural diversities beyond compare with any other type of synthetic material. These features conform an excellent platform to engineer these porous materials with other functionalities like tunable optical and electrical properties or a rich host-guest chemistry amenable to chemical modification of their porous scaffolds, to access a new world of possibilities with MOFs playing an emerging role as multipurpose catalysts.

This PROMETEO excellence project will use this chemical approach to target two applications of scientific and social relevance like energy conversion and metal cluster catalysis. MOFs are still underexplored in this context and we are confident the goals pursued might represent a significant advance in the field that helps changing the conception of MOFs, sometimes perceived simply as aesthetically pleasant crystal structures, into advanced porous materials with important implications in high-impact catalysis.

Research

Hierarchically we will approach three general objectives

First, we aim to demonstrate that compared to classical inorganic semiconductors, MOFs can play a significant role as advanced porous photo-catalysts with tunable efficiency by chemical engineering of their optical activity and electrical conductivity. In parallel, we aim to exploit the combination of chemical stability, electrical conductivity and porosity deployed by these crystalline frameworks to unleash their potential in electroreduction CO2 reactions. Finally, we plan to go be-yond the state-of-the-art and use MOFs as crystalline platforms to template the growth, stabilise and characterise SNMCs directly into their pores by mastering the host-guest dynamical recognition processes involved. Also important, the PROMETEO excellence project recognises the potential of the pursued goals for direct transfer to industrial application. Accordingly, we also aim to adapt the synthesis of the MOF materials identified as more relevant into more efficient production methodologies that allow for efficient multi-gram synthesis with optimum cost.

Team will de-velop the project are women57%
Doctors of the working team77%
PhD level46%
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Our Team

Carlos Martí Gastaldo

Instituto de Ciencia Molecular (ICMol), Valencia

Emilio Pardo

Instituto de Ciencia Molecular (ICMol), Valencia

Núria López

Institute of Chemical Research of Catalonia (ICIQ)

Sergio Tatay

Instituto de Ciencia Molecular (ICMol), Valencia

Donatella Armentano

Università della Calabria, Italy

Publications

Single–atom Cu catalysts for the oxidative coupling of styrenes with aryl sulfones: from salts and zeolites to MOFs

“Single–atom Cu catalysts for the oxidative coupling of styrenes with aryl sulfones: from salts and zeolites to MOFs” Bilanin C., Zheng Y., Vidal-Moya, A., Pardo, E., Mon, M., Leyva-Pérez A Molecular Catalysis, 553, 113786 (2024). Read More

A MOF-supported Pd1-Au1 dimer catalyzes the semi-hydrogenation reaction of acetylene in ethylene with a nearly barrier-less activation energy

“A MOF-supported Pd1-Au1 dimer catalyzes the semi-hydrogenation reaction of acetylene in ethylene with a nearly barrier-less activation energy” Ballesteros-Soberanas, J., Martín, N., Bacic, M., Tiburcio, E., Mon, M., Hernandez-Garrido, J. C., Marini, C., Boronat, M., Ferrando-Soria, J., Armentano, D., Pardo, E. & Leyva-Pérez A Nature catalysis, Accepted for publication (2024) Read More

Time-Resolved Control of Nanoparticle Integration in Titanium-Organic Frameworks for Enhanced Catalytic Performance

“Time-Resolved Control of Nanoparticle Integration in Titanium-Organic Frameworks for Enhanced Catalytic Performance” Fernández-Conde, C.; Zheng, Y.; Mon, M.; Ribera, A.; Leyva-Pérez, A.; Martí-Gastaldo, C Chem. Sci., Advance Article (2024). Read More

News

International Day of Women and Girls in Science

The women from our group have participated in the celebration of the “International Day of Women and Girls in Science” that took place on the 11th of February 2022. On this day, dedicated to celebrate women in science, they joined the CEIP Bertomeu Llorens i Royo (Catarroja) in order to present children the significance of [...] Read More
Location

Instituto de Ciencia Molecular
Catedrático José Beltrán 2
CP 46980, Paterna (Spain)

Make a Call

Tel: +34 96 354 4421
Fax: +34 96 354 3273

Send a Mail

carlos.marti@uv.es

Contact